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Pd-Ni nanoparticles supported on titanium oxide as effective catalysts for Suzuki-Miyaura coupling reactions

Dongxu Han, Zhiguo Zhang, Zongbi Bao, Huabin Xing, Qilong Ren

Frontiers of Chemical Science and Engineering 2018, Volume 12, Issue 1,   Pages 24-31 doi: 10.1007/s11705-017-1669-4

Abstract: We have successfully prepared a series of Pd-Ni/TiO catalysts by a one-step impregnation-reduction methodAmong these catalysts with different compositions of Ni and Pd, the one with the Ni:Pd ratio of 2.95Small monodispersed Pd-Ni bimetallic nanoparticles were loaded on the surface of titanium oxide nanopowderis Ni(II).The prepared Pd-Ni/TiO exhibited enhanced catalytic activity compared to an equal amount of Pd/TiO

Keywords: Pd-Ni bimetallic nanoparticles     nanocatalysis     Suzuki-Miyaura reaction     titanium oxide    

Dechlorination of dichlorodiphenyltrichloroethane (DDT) by Fe/Pd bimetallic nanoparticles: Comparison

Kubra Ulucan-Altuntas, Eyup Debik

Frontiers of Environmental Science & Engineering 2020, Volume 14, Issue 1, doi: 10.1007/s11783-019-1196-2

Abstract: DDT undergoes dechlorination via Fe/Pd bimetallic nanoparticle.The oxidation effect of nZVI on DDT is greatly improved when Pd is dopped.In this study, the bimetallic Fe/Pd nanoparticle was synthesized using the catalytic element palladiumnanoparticles and the difference with nZVI was determined.The highest possible initial DDT concentration for the treatment with Fe/Pd bimetallic nanoparticle was

Keywords: Persistent organic pollutants     nZVI     Bimetallic nanoparticle     Organochlorine pesticides     DDT    

Removing polybrominated diphenyl ethers in pure water using Fe/Pd bimetallic nanoparticles

Min ZHANG,Jian LU,Zhencheng XU,Yiliang HE,Bo ZHANG,Song JIN,Brian BOMAN

Frontiers of Environmental Science & Engineering 2015, Volume 9, Issue 5,   Pages 832-839 doi: 10.1007/s11783-015-0778-x

Abstract: To enhance the degradation efficiency, ZVI/Palladium bimetallic nanoparticles (nZVI/Pd) were synthesizedApproximately 90% of BDE209 was rapidly removed by nZVI/Pd within 80 min, whereas about 25% of BDE209Degradation of BDE209 by nZVI/Pd fits pseudo-first-order kinetics.The degradation intermediates of BDE209 by nZVI/Pd were identified and the degradation pathways wereResults from this study suggest that nZVI/Pd may be an effective tool for treating polybrominated diphenyl

Keywords: degradation     bimetallic nanoparticles     nanoscale zero-valent iron     polybrominated diphenyl ethers    

Ni-Co bimetallic catalyst for CH

Xiaohong LI, Jun AI, Wenying LI, Dongxiong LI

Frontiers of Chemical Science and Engineering 2010, Volume 4, Issue 4,   Pages 476-480 doi: 10.1007/s11705-010-0512-y

Abstract: A co-precipitation method was employed to prepare Ni/Al O -ZrO , Co/Al O -ZrO and Ni-Co/Al O -ZrO catalystsNi-Co/Al O -ZrO bimetallic catalyst has good performance in the reduction of active components Ni, CoCompared with mono-metallic catalyst, bimetallic catalyst could provide more active sites and CO adsorptionAccording to the CH -CO -TPSR, there were 80.9% and 81.5% higher CH and CO conversion over Ni-Co/AlThe high activity and excellent anti-coking of the Ni-Co/Al O -ZrO catalyst were closely related to

Keywords: Ni-Co bimetallic catalyst     composite support     CH4 reforming with CO2    

The synergic effects of highly selective bimetallic Pt-Pd/SAPO-41 catalysts for the

Guozhi Jia, Chunmu Guo, Wei Wang, Xuefeng Bai, Xiaomeng Wei, Xiaofang Su, Tong Li, Linfei Xiao, Wei Wu

Frontiers of Chemical Science and Engineering 2021, Volume 15, Issue 5,   Pages 1111-1124 doi: 10.1007/s11705-020-2031-9

Abstract: The hydroisomerization of -hexadecane over Pt-Pd bimetallic catalysts is an effective way to produceThis work reports a useful preparation method of bimetallic bifunctional catalysts by a co-impregnationFurthermore, monometallic catalysts with loading either Pt or Pd are also prepared for comparison./SAPO-41Pd/SAPO-41 (prepared by sequential impregnation)Pd/SAPO-41 (prepared by co-impregnationOwing to the synergic effects between Pt and Pd, the Pt-Pd/SAPO-41 catalyst prepared by the co-impregnation

Keywords: SAPO-41 molecular sieve     Pt-Pd bimetallic site     bifunctional catalysts     n-hexadecane     hydroisomerization    

In situ formation of bimetallic FeNi nanoparticles on sand through green technology: Application for

Ravikumar KVG, Debayan Ghosh, Mrudula Pulimi, Chandrasekaran Natarajan, Amitava Mukherjee

Frontiers of Environmental Science & Engineering 2020, Volume 14, Issue 1, doi: 10.1007/s11783-019-1195-3

Abstract: • In situ preparation of FeNi nanoparticles on the sand via green synthesis approach. • Removal ofIn this study, FeNi nanoparticles were green synthesized using Punica granatum (pomegranate) peel extract, and these nanoparticles were also formed in situ over quartz sand (GS-FeNi) for removal of tetracycline

Keywords: GS-FeNi nanoparticles     Tetracycline removal     Re-usability     Residual toxicity     Column studies    

2-Aminopyridine functionalized cellulose based Pd nanoparticles: An efficient and ecofriendly catalyst

Peibo Hu,Yahao Dong,Xiaotian Wu,Yuping Wei

Frontiers of Chemical Science and Engineering 2016, Volume 10, Issue 3,   Pages 389-395 doi: 10.1007/s11705-016-1575-1

Abstract: good yields, and easily recycled by simple filtration after reaction without the loss of metal Pd.

Keywords: cellulose-supported     2-aminopyridine     palladium nanoparticles     ecofriendly catalyst     Suzuki cross-coupling    

Ultrafine Fe-modulated Ni nanoparticles embedded within nitrogen-doped carbon from Zr-MOFs-confined conversion

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 7,   Pages 1114-1124 doi: 10.1007/s11705-021-2087-1

Abstract: In this study, ultrafine Fe-modulated Ni nanoparticles embedded in a porous Ni-doped carbon matrix weremetal-organic-frameworks, in which 2,2′-bipyridine-5,5′-dicarboxylate operating as a ligand can coordinate with NiThis strategy allows formation of Fe-modulated Ni nanoparticles with a uniform dimension of about 2 nm

Keywords: metal-organic framework     pyrolysis     ultrafine     Fe-modulated Ni nanoparticles     oxygen evolution reaction    

Nitrogen-doped carbon black supported Pd nanoparticles as an effective catalyst for formic acid electro-oxidation

Na SUN, Minglei WANG, Jinfa CHANG, Junjie GE, Wei XING, Guangjie SHAO

Frontiers in Energy 2017, Volume 11, Issue 3,   Pages 310-317 doi: 10.1007/s11708-017-0491-5

Abstract: Pd nanoparticles supported on nitrogen doped carbon black (Vulcan XC-72R) with two different levels ofThe results indicate that the different nitrogen doping contents in Pd/N-C catalysts have a significantA higher N content facilitates the uniform dispersion of Pd nanoparticles on carbon black with narrowThe peak current density of the Pd/N-C (high) catalyst is 1.27 and 2.31 times that of the Pd/N-C (low) and homemade Pd/C-H catalyst.

Keywords: formic acid electro-oxidation     nitrogen doped     oxidized carbon     nitrogen content    

Bimetallic Ni-Fe catalysts derived from layered double hydroxides for CO methanation from syngas

Honggui Tang, Shuangshuang Li, Dandan Gong, Yi Guan, Yuan Liu

Frontiers of Chemical Science and Engineering 2017, Volume 11, Issue 4,   Pages 613-623 doi: 10.1007/s11705-017-1664-9

Abstract: Facing the challenges, bimetallic catalysts with different Fe content derived from layered double hydroxideNanoparticles of Ni-Fe alloy were supported on mixed oxides of aluminium and magnesium after calcinationcatalysts except for the Ni4Fe-red catalyst.to carbon formation compared with the Ni0Fe-red catalyst.only inhibits the sintering of nanoparticles but restrains the formation of Ni clusters.

Keywords: methanation     layered double hydroxide     bimetal Ni-Fe alloy     sintering     carbon deposition    

Investigation of the preparation methodologies of Pd-Cu single atom alloy catalysts for selective hydrogenation

Xinxiang Cao,Arash Mirjalili,James Wheeler,Wentao Xie,Ben W.-L. Jang

Frontiers of Chemical Science and Engineering 2015, Volume 9, Issue 4,   Pages 442-449 doi: 10.1007/s11705-015-1547-x

Abstract: Galvanic replacement, co-impregnation and sequential impregnation have been employed to prepare Pd-Cubimetallic catalysts with less than 1 wt-% Cu and ca. 0.03 wt-% Pd for selective hydrogenation of acetylenefield-scanning transmission electron microscopy (HAADF-STEM) and H chemisorption results confirmed that Pd-Cusingle-atom alloy structures were constructed in all three bimetallic catalysts.

Keywords: H2 pulse chemisorption     palladium-copper bimetallic catalyst     single atom alloy     acetylene hydrogenation    

Room-temperature hydrogenation of halogenated nitrobenzenes over metal–organic-framework-derived ultra-dispersed Ni

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 12,   Pages 1782-1792 doi: 10.1007/s11705-022-2220-9

Abstract: Ultra-dispersed Ni nanoparticles (7.5 nm) on nitrogen-doped carbon nanoneedles (Ni@NCNs) were preparedby simple pyrolysis of Ni-based metal–organic-framework for selective hydrogenation of halogenated nitrobenzenesNi@NCNs were systematically characterized by wide analytical techniques.mild conditions (90 °C, 1.5 MPa H2), showing obvious superiority compared with reported Ni-basedMoreover, Ni@NCNs-600 afforded good tolerance to various nitroarenes substituted by sensitive groups

Keywords: halogenated nitrobenzenes     room-temperature hydrogenation     Ni nanoparticles     nitrogen-doped carbon nanoneedles    

Synthesis, physicochemical characterizations and catalytic performance of Pd/carbon-zeolite and Pd/carbon-CeO

Zeinab JAMALZADEH, Mohammad HAGHIGHI, Nazli ASGARI

Frontiers of Environmental Science & Engineering 2013, Volume 7, Issue 3,   Pages 365-381 doi: 10.1007/s11783-013-0520-5

Abstract: In this work, xylene removal from waste gas streams was investigated via catalytic oxidation over Pd/carbon-zeolite and Pd/carbon-CeO nanocatalysts.

Keywords: Pd/carbon-CeO2     Pd/carbon-zeolite     pine cone     ZnCl2     catalytic oxidation     xylene    

3D Network nanostructured NiCoP nanosheets supported on N-doped carbon coated Ni foam as a highly active

Miaomiao Tong, Lei Wang, Peng Yu, Xu Liu, Honggang Fu

Frontiers of Chemical Science and Engineering 2018, Volume 12, Issue 3,   Pages 417-424 doi: 10.1007/s11705-018-1711-1

Abstract: self-supported electrode composed of 3D network nanostructured NiCoP nanosheets grown on N-doped carbon coated Ni

Keywords: bimetallic phosphides     N-doped carbon     self-support     hydrogen evolution     oxygen evolution    

Bamboo-like -doped carbon nanotubes encapsulating M(Co, Fe)-Ni alloy for electrochemical production of

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 4,   Pages 498-510 doi: 10.1007/s11705-021-2082-6

Abstract: Herein, a series of N-doped carbon nanotubes encapsulating binary alloy nanoparticles (MxNi-NCNT, M= Fe, Co) were successfully fabricated through the co-pyrolysis of melamine andThe MxNi-NCNT samples exhibited bamboo-like nanotubular structures with a large specificcompositions and modifying the electronic structure of the carbon nanotube through the encapsulated metal nanoparticlesand Co2Ni-NCNT, respectively, over a potential window of –0.8 to –1.2 V versus the

Keywords: electrochemical reduction of CO2     syngas     N-doped carbon nanotubes     encapsulated alloy nanoparticles    

Title Author Date Type Operation

Pd-Ni nanoparticles supported on titanium oxide as effective catalysts for Suzuki-Miyaura coupling reactions

Dongxu Han, Zhiguo Zhang, Zongbi Bao, Huabin Xing, Qilong Ren

Journal Article

Dechlorination of dichlorodiphenyltrichloroethane (DDT) by Fe/Pd bimetallic nanoparticles: Comparison

Kubra Ulucan-Altuntas, Eyup Debik

Journal Article

Removing polybrominated diphenyl ethers in pure water using Fe/Pd bimetallic nanoparticles

Min ZHANG,Jian LU,Zhencheng XU,Yiliang HE,Bo ZHANG,Song JIN,Brian BOMAN

Journal Article

Ni-Co bimetallic catalyst for CH

Xiaohong LI, Jun AI, Wenying LI, Dongxiong LI

Journal Article

The synergic effects of highly selective bimetallic Pt-Pd/SAPO-41 catalysts for the

Guozhi Jia, Chunmu Guo, Wei Wang, Xuefeng Bai, Xiaomeng Wei, Xiaofang Su, Tong Li, Linfei Xiao, Wei Wu

Journal Article

In situ formation of bimetallic FeNi nanoparticles on sand through green technology: Application for

Ravikumar KVG, Debayan Ghosh, Mrudula Pulimi, Chandrasekaran Natarajan, Amitava Mukherjee

Journal Article

2-Aminopyridine functionalized cellulose based Pd nanoparticles: An efficient and ecofriendly catalyst

Peibo Hu,Yahao Dong,Xiaotian Wu,Yuping Wei

Journal Article

Ultrafine Fe-modulated Ni nanoparticles embedded within nitrogen-doped carbon from Zr-MOFs-confined conversion

Journal Article

Nitrogen-doped carbon black supported Pd nanoparticles as an effective catalyst for formic acid electro-oxidation

Na SUN, Minglei WANG, Jinfa CHANG, Junjie GE, Wei XING, Guangjie SHAO

Journal Article

Bimetallic Ni-Fe catalysts derived from layered double hydroxides for CO methanation from syngas

Honggui Tang, Shuangshuang Li, Dandan Gong, Yi Guan, Yuan Liu

Journal Article

Investigation of the preparation methodologies of Pd-Cu single atom alloy catalysts for selective hydrogenation

Xinxiang Cao,Arash Mirjalili,James Wheeler,Wentao Xie,Ben W.-L. Jang

Journal Article

Room-temperature hydrogenation of halogenated nitrobenzenes over metal–organic-framework-derived ultra-dispersed Ni

Journal Article

Synthesis, physicochemical characterizations and catalytic performance of Pd/carbon-zeolite and Pd/carbon-CeO

Zeinab JAMALZADEH, Mohammad HAGHIGHI, Nazli ASGARI

Journal Article

3D Network nanostructured NiCoP nanosheets supported on N-doped carbon coated Ni foam as a highly active

Miaomiao Tong, Lei Wang, Peng Yu, Xu Liu, Honggang Fu

Journal Article

Bamboo-like -doped carbon nanotubes encapsulating M(Co, Fe)-Ni alloy for electrochemical production of

Journal Article